The 35-year-old, who is currently without a club, will feature for the reserves with the prospect of re-signing with Arsenal.
Arsenal boss Arsene Wenger has previously ruled out a move for Campbell.
A short statement on the club’s official website said: “Tonight’s reserve team to face West Ham United at Upton Park features Sol Campbell, who plays on a Reserve League registration, with a view to a permanent move back to Arsenal Football Club.”