Martial came off the bench and scored in the 3-1 win over Liverpool on Saturday.
Louis van Gaal has hinted that he was not keen to start the 19-year-old in the early stages of his career at United.
PSV Eindhoven vs. Manchester United starting line-ups:
PSV: Zoet; Arias, Bruma, Moreno, Brenet; Hendrix, Propper; Guardado, Narsingh, De Jong, Lestienne.
Subs: Pasveer, Pereiro, Schaars, Poulsen, Locadia, Vloet, De Wijs.
Manchester United: De Gea; Darmian, Smalling, Blind, Shaw; Schweinsteiger, Herrera; Young, Mata, Memphis; Martial.
Subs: Romero, McNair, Rojo, Carrick, Schneiderlin, Valencia, Fellaini.
